Noble-metal catalysts are used in many processes in the chemical industry. A reduction of the amount of noble metal required for their production is an important contribution to a sustainable resource use. “Our approach will significantly improve the catalyst stability and ensure the formation of active noble-metal clusters even with a very low amount of noble metal used,” says Dr. Daria Gashnikova from KIT’s Institute for Chemical Technology and Polymer Chemistry (ITCP), who is the lead author of the study. To obtain the best possible catalytic performance using the smallest possible amount of noble metals, the ITCP researchers investigated frequently used supported catalysts atom by atom. In these supported catalysts, the material where the reaction takes place is finely distributed on the support as small nanoparticles. These clusters are dynamic and change their structure depending on the reaction conditions. They can combine with each other and grow into larger particles so that fewer surface atoms are available for the reaction. However, they can also break down into single atoms that are ineffective on their own. Both phenomena reduce the catalytic performance. The novel concept developed by the ITCP researches solves this problem by taking advantage of the varying interactions of noble metals with different support materials.
Nanometer-sized palladium particles on ceria “islands” make noble-metal catalysts stable and efficient.
Foto: ITCP, KIT
Newly Designed Support Material – Noble-Metal Atoms Gather to Form Ceria “Islands”
“Noble metals, such as Palladium, tend to bond intensely with ceria, but hardly interact with aluminum oxide,” explains Gashnikova. “This is why we applied palladium to tiny ceria ‘nano-islands’ which in turn were finely distributed on aluminum oxide,” says the scientist. The optimization of the support material ensures that the noble metal atoms preferably form sites on the ceria islands. The distance between the islands on the one hand and the limited mobility of ceria-bound palladium on the other hand prevent both the formation of excessively large clusters and the decomposition of the palladium into single atoms. The size of the noble-metal clusters is defined by the number of noble-metal atoms on the individual ceria islands. “Our dream is to walk the fine line during the entire lifetime of the catalyst, and, if possible, to stabilize small particles consisting of only ten to 50 atoms,” says Professor Jan-Dierk Grunwaldt, member of the ITCP Management team and spokesperson of the Collaborative Research Center (CRC) 1441, “TrackAct”.
